Identifying the Metallic State of Rh Catalyst on Boron Nitride during Partial Oxidation of Methane by Using the Product Molecule as the Infrared Probe
نویسندگان
چکیده
The partial oxidation of methane (POM) is a promising method for converting to syngas. transition metal supported on boron nitride (BN) has recently been studied as part catalog emerging catalysts. However, the chemical state BN during reforming still in debate. In this work, we report rhodium catalyst (Rh/BN) POM, with exceptional activity and long-term stability at 600 °C 230 h. Rh/BN was investigated by X-ray diffraction, photoelectron spectroscopy, Raman transmission electron microscopy, diffuse reflectance infrared Fourier transformed spectroscopy (DRIFTS). As revealed situ DRIFTS, band (2020 cm?1) product molecule, CO, adsorbed Rh, probe confirms metallic Rh POM reaction. addition, results DRIFTS indicate that reactive gaseous environment would react form B-OH B-H, which synergistically boost activity.
منابع مشابه
the effect of e-64 on the developmental competence of sheep cocs during in vitro maturation
in the present study, the effect of e-64 at different concentrations (0.5, 1, 5 and 10 µm) added to (1) the ivm medium on oocyte nuclear maturation and developmental competence of ovine oocytes, and (2) to the ivc medium on embryonic development of ovine embryos were investigated.
the role of task-based techniques on the acquisition of english language structures by the intermediate efl students
this study examines the effetivenss of task-based activities in helping students learn english language structures for a better communication. initially, a michigan test was administered to the two groups of 52 students majoring in english at the allameh ghotb -e- ravandi university to ensure their homogeneity. the students scores on the grammar part of this test were also regarded as their pre...
15 صفحه اولthe effect of using model essays on the develpment of writing proficiency of iranina pre-intermediate efl learners
abstract the present study was conducted to investigate the effect of using model essays on the development of writing proficiency of iranian pre-intermediate efl learners. to fulfill the purpose of the study, 55 pre- intermediate learners of parsa language institute were chosen by means of administering proficiency test. based on the results of the pretest, two matched groups, one as the expe...
the effect of using visual aids on the development of speech act of disagreement among iranian intermediate efl learners
abstract the present study tried to investigate the effect of visual aids (films) on the development of the speech act of disagreement among iranian efl intermediate learners. to this end, the researcher selected 40 homogeneous intermediate learners based on their scores on oxford placement test. .the subjects then divided into control group and experimental group. both classes were tested by ...
the effect of taftan pozzolan on the compressive strength of concrete in the environmental conditions of oman sea (chabahar port)
cement is an essential ingredient in the concrete buildings. for production of cement considerable amount of fossil fuel and electrical energy is consumed. on the other hand for generating one tone of portland cement, nearly one ton of carbon dioxide is released. it shows that 7 percent of the total released carbon dioxide in the world relates to the cement industry. considering ecological issu...
ذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Catalysts
سال: 2022
ISSN: ['2073-4344']
DOI: https://doi.org/10.3390/catal12101146